Microsoft word - ammunition utilizing monolithic bullets

MATERIAL SAFETY
Hornady® Ammunition with
DATA SHEET
Monolithic Projectiles
MSDS DATE: 7/29/13
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Hornady® Ammunition Utilizing Monolithic Projectiles

TRADE NAMES: Applies to any Hornady® centerfire rifle or pistol ammunition loaded with GMX® or MonoFlex® bullets.
SYNONYMS: Custom™, Light Mag™, Heavy Mag™, Superformance®, LeverEvolution®

MANUFACTURER: Hornady Manufacturing Company
ADDRESS: 3625 W. Old Potash Hwy
HMIS® Ratings

EMERGENCY PHONE: 800-338-3220
CHEMTREC PHONE: 800-424-9300 CHEMTREC INTERNATIONAL: +703-527-3887
FLAMMABILITY
OTHER CALLS: (308) 382-1390
PERSONAL PROTECTION
PRODUCT USE: Firearm ammunition
PREPARED BY: M. Spencer
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
HAZARDOUS INGREDIENTS:

OSHA PEL ACGIH TLV
CAS# %WT 313 TWA (mg/m3) TWA (mg/m3)

SECTION 2 NOTES:

SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: Do not take internally. Keep away from sources of ignition. Explosive. Avoid subjecting product to physical
shock/ impact. Byproducts of use may be harmful if inhaled.

ROUTES OF ENTRY: Inhalation, ingestion, eyes

POTENTIAL HEALTH EFFECTS
EYES: Use of product may result in airborne particles/fragments. Particles/fragments may cause irritation or eye injury if safety glasses
are not used.

SKIN: Minimal irritation. Wash hands after use and before eating, drinking or smoking to reduce chances of ingestion.

INGESTION: Not a likely route of exposure.

INHALATION: Under normal conditions of use, inhalation is not expected to be a siginificant route of exposure.

ACUTE HEALTH HAZARDS: Particulates from firing: Eye irritation or injury, skin irritation. Inhaling large amounts of copper dust may cause
nasal and respiratory irritation as well as nausea and vomiting. Zinc ingestion may cause headache, nausea, fever.

CHRONIC HEALTH HAZARDS: Long-term exposure to copper dust/fumes may affect liver and kidneys. May also lead to dermal allergic
reaction.

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Respiratory conditions easily aggravated by airborne dust or
particulates.

CARCINOGENICITY
OSHA: No IARC: No
OTHER: No
PAGE 1 OF 5
MATERIAL SAFETY
Hornady® Ammunition with
DATA SHEET
Monolithic Projectiles
MSDS DATE: 7/29/13

SECTION 3 NOTES: The physical form of these products makes it unlikely that exposure of any significant amount will occur. Exposure is
very unlikely during normal handling and firing. Firing ammunition will produce small particles that could contain minute amounts of the
chemicals listed in section 1. Greatest exposure will occur if firing takes place indoors. See section 8 for exposure controls.
SECTION 4: FIRST AID MEASURES

EYES: Immediately flush out fume or particles with large amounts of water for at least 15 minutes. If irritation develops, call physician.

SKIN: Wash affected skin thoroughly with soap and water.

INGESTION: If ingested, call physician immediately.

INHALATION: If signs of lung irritation occur, remove victim to fresh air immediately. If respiration has stopped administer CPR and get
medical attention immediately.

SECTION 4 NOTES:

SECTION 5: FIRE-FIGHTING MEASURES

FLAMMABLE LIMITS IN AIR, UPPER: N/A
(% BY VOLUME) LOWER: N/A

FLASH POINT:
F: N/A
C: N/A
METHOD USED: N/A

AUTOIGNITION TEMPERATURE:
F: N/A
C: N/A

HMIS HAZARD CLASSIFICATION
HEALTH: 0 FLAMMABILITY: 0 Physical: 1
OTHER:
EXTINGUISHING MEDIA: Water preferably, otherwise carbon dioxide or dry chemical.

SPECIAL FIRE FIGHTING PROCEDURES: Flood area with water to cool exposed product and extinguish fire.

UNUSUAL FIRE AND EXPLOSION HAZARDS: Classified as explosive threat. Low to moderate velocity projectiles and localized
detonations (generally confined to the immediate vicinity of the packages). Use normal fire fighting equipment including face shield and
SCBA. If product is likely to ignite, withdraw all personnel to a distance of at least 50 ft. and fight fire using normal precautions.

HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, nitrogen oxides.
SECTION 6: ACCIDENTAL RELEASE MEASURES

ACCIDENTAL RELEASE MEASURES: Spills will not normally require emergency response. Do not expose product to mechanical shock,
electrical shock or impact. Spilled product can be pickup up by any non-spark, non-impact tools/methods. If spill is large or other assistance
is required, call 800-338-3220 or CHEMTREC at 800-424-9300.

SECTION 6 NOTES: If cartridges are damaged or ruptured be very careful to avoid all sources of ignition.
PAGE 2 OF 5
MATERIAL SAFETY
Hornady® Ammunition with
DATA SHEET
Monolithic Projectiles
MSDS DATE: 7/29/13
SECTION 7: HANDLING AND STORAGE

HANDLING AND STORAGE: Store in a cool, dry location. Do not expose to excessive heat, flame or other sources of ignition. Avoid
mechanical shock and electrical discharge. Refer to section 10 for reactivity information.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: Use of proper range filtration and airflow as well as sound deadening material for indoor firing.

VENTILATION: Use mechanical ventilation if product is utilized indoors to maintain exposures below PEL. Ventilation should not be required
outdoors.

RESPIRATORY PROTECTION: Not normally needed.

EYE PROTECTION: Safety glasses

SKIN PROTECTION: Not normally needed

OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Use adequate hearing protection when using firearms.

WORK HYGIENIC PRACTICES: Wash hands thoroughly after use and before eating, drinking or using tobacco.

SECTION 8 NOTES: WARNING: FIRED PROJECTILES MAY CAUSE SERIOUS INJURY OR DEATH. Use ammunition ONLY in
firearms that are of the correct caliber and in good condition. ALWAYS keep the muzzle pointed in a safe direction. Projectiles have
extremely long range, always be certain to have an adequate backstop. To avoid ricochet, do not fire at water, rocks or other hard or
flat surfaces.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE: Brass case. Copper projectile with rigid polymer or resilient elastomer tip.

ODOR: None

PHYSICAL STATE: Solid
pH AS SUPPLIED: N/A
pH (Other): N/A
BOILING POINT: N/A
MELTING POINT: N/A
FREEZING POINT: N/A
VAPOR PRESSURE (mmHg): N/A
VAPOR DENSITY (AIR = 1): N/A
SPECIFIC GRAVITY (H2O = 1): N/A
EVAPORATION RATE: N/A

SOLUBILITY IN WATER: Insoluble
PERCENT SOLIDS BY WEIGHT: 100%
PERCENT VOLATILE: N/A
VOLATILE ORGANIC COMPOUNDS (VOC): N/A
MOLECULAR WEIGHT: N/A, Mixture
VISCOSITY: N/A
SECTION 9 NOTES:
PAGE 3 OF 5
MATERIAL SAFETY
Hornady® Ammunition with
DATA SHEET
Monolithic Projectiles
MSDS DATE: 7/29/13
SECTION 10: STABILITY AND REACTIVITY

STABILITY: Stable under normal conditions.

CONDITIONS TO AVOID (STABILITY): Mechanical shock, electrical discharge, extreme heat.

INCOMPATIBILITY (MATERIAL TO AVOID): Acids, class A and B explosives, caustics, strong oxidizers.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: Carbon monoxide, nitrogen oxides.

HAZARDOUS POLYMERIZATION: Will not occur

SECTION 10 NOTES:

SECTION 11: TOXICOLOGICAL INFORMATION

TOXICOLOGICAL INFORMATION:
Nitrocellulose
Nitroglycerine
LD-50 (oral)
(inhalation)


SECTION 11 NOTES:
SECTION 12: ECOLOGICAL INFORMATION

ECOLOGICAL INFORMATION: This product has no ecological information available. Individual component information is as follows:
Copper: Toxic to aquatic species. Concentration required for toxicity varies with water chemistry, light transmittance and other
factors. Generally accepted level for aquatic toxicity is >1.0mg/L.
Nitrocellulose: LC-50>1,000 mg/L (aquatic invertebrates, fish, algae)
Nitroglycerine: LC-50 (96 hour) 1.228 mg/L (bluegill)
Zinc: Depending on conditions, as little as .13 mg/L may be toxic to some species.
SECTION 13: DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD: Product that has become waste must be considered hazardous and disposed of accordingly. The user of this
product is responsible for seeing that it is disposed of in accordance with all federal, state and local laws. For more information regarding
disposal of this product contact the manufacturer.

RCRA HAZARD CLASS: D003, depending on condition.
_________________________________________________________________________________________________________________
SECTION 14: TRANSPORT INFORMATION

U.S. DEPARTMENT OF TRANSPORTATION
PROPER SHIPPING NAME: Cartridges, Small Arms
HAZARD CLASS: 1.4 S
ID NUMBER: UN 0012
PACKING GROUP: II
LABEL STATEMENT: None for highway/ water/ rail; 1.4 placard for individual packages over 1001 lbs.

AIR TRANSPORTATION
PROPER SHIPPING NAME: Cartridges, Small Arms
PAGE 4 OF 5
MATERIAL SAFETY
Hornady® Ammunition with
DATA SHEET
Monolithic Projectiles
MSDS DATE: 7/29/13

HAZARD CLASS: 1.4S
ID NUMBER: UN 0012
PACKING GROUP: II
LABEL STATEMENTS: 1.4S label


SECTION 14 NOTES: Product may be reclassified domestically as ORM-D (through 12/31/2020) for ground transportation; or as hazardous
material in Limited Quantities (beginning 1/1/11) if packaged per 49 CFR 173.63. Package may then be marked ORM-D per 49 CFR 172.316;
or as Limited Quantities per 49 CFR 172.315.
SECTION 15: REGULATORY INFORMATION

U.S. FEDERAL REGULATIONS
TSCA (TOXIC SUBSTANCE CONTROL ACT): Components are listed on the Toxic Substances Control Act Inventory.

CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): CERCLA RQ’s: Copper= 5,000 lbs., 2,4
Dinitrotoluene= 10 lbs., Nickel= 100 lbs., Nitroglycerin= 10 lbs., Zinc= 1,000 lbs. Reporting is not required for metals (copper, antimony, nickel and zinc) if the mean diameter of the particle is greater than .004 inches.
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT): Nitroglycerin if above threshold.

311/312 HAZARD CATEGORIES: Release of Pressure

313 REPORTABLE INGREDIENTS: see section 1

STATE REGULATIONS (Right-To-Know):
New Jersey: Copper, Nitrocellulose, Nitroglycerin, Zinc Pennsylvania: Copper, Nitrocellulose, Nitroglycerin, Massachusetts: Copper, Nitrocellulose, Nitroglycerin, Zinc
SECTION 15 NOTES: Not intended to be all-inclusive- only selected regulations are represented.

SECTION 16: OTHER INFORMATION

DISCLAIMER: Hornady Manufacturing Company believes the information contained in this MSDS to be accurate and complete as of the date
of publication, however no responsibility is assumed for the suitability of this data to the end user or for omissions or errors in its content. This
sheet should be provided to all who use, handle, transport or store the material in question.
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Source: http://www.hornady.com/assets/files/msds/Ammunition%20Utilizing%20Monolithic%20Bullets.pdf