Chemwatch new zealand msds 21-5472

JASOL GRILLER
Chemwatch Material Safety Data Sheet
For Domestic Use Only.
CHEMWATCH 21-5472
Issue Date: 7-Jul-2009
Version No:2.0
CD 2010/2 Page 1 of 6
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
JASOL GRILLER
STATEMENT OF HAZARDOUS NATURE
Considered a Hazardous Substance according to the criteria of the New Zealand Hazardous Substances New Organisms
legislation.
PROPER SHIPPING NAME
CORROSIVE LIQUID, N.O.S.(contains sodium hydroxide)
PRODUCT USE
Grill and oven, smokehouse, and other heavy duty cleaning.
SUPPLIER
Company: Jasol
Section 2 - HAZARDS IDENTIFICATION
GHS Classification
Carcinogen Category 2
Metal Corrosion Category 1
Serious Eye Damage Category 1
Skin Corrosion/Irritation Category 1B
EMERGENCY OVERVIEW
HAZARD
DANGER
Determined by Chemwatch using GHS/HSNO criteria:
6.7B 8.1A 8.2B 8.3A
Suspected of causing cancer
May be corrosive to metals
Causes severe skin burns and eye damage
Causes serious eye damage
PRECAUTIONARY STATEMENTS
Prevention
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep only in original container.
Do not breathe dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Wear protective gloves/protective clothing/eye protection/face protection.
Use personal protective equipment as required.
Response
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
continued.
JASOL GRILLER
Chemwatch Material Safety Data Sheet
For Domestic Use Only.
CHEMWATCH 21-5472
Issue Date: 7-Jul-2009
Version No:2.0
CD 2010/2 Page 2 of 6
Section 2 - HAZARDS IDENTIFICATION
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF exposed or concerned: Get medical advice/ attention.
Immediately call a POISON CENTER or doctor/physician.
Wash contaminated clothing before reuse.
Absorb spillage to prevent material damage.
Storage
Store locked up.
Store in corrosive resistant container or with a resistant inner liner.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
Section 4 - FIRST AID MEASURES
NEW ZEALAND POISONS INFORMATION CENTRE 0800 POISON (0800 764 766)NZ EMERGENCY SERVICES: 111 SWALLOWED
• For advice, contact a Poisons Information Centre or a doctor at once.
• Urgent hospital treatment is likely to be needed.
• If swallowed do NOT induce vomiting.
• If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
EYE
■ If this product comes in contact with the eyes:
• Immediately hold eyelids apart and flush the eye continuously with running water.
• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower
lids.
• Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
• Transport to hospital or doctor without delay.
SKIN
■ If skin or hair contact occurs:
• Immediately flush body and clothes with large amounts of water, using safety shower if available.
• Quickly remove all contaminated clothing, including footwear.
• Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre.
• Transport to hospital, or doctor.
INHALED
• If fumes or combustion products are inhaled remove from contaminated area.
• Lay patient down. Keep warm and rested.
• Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
• Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained.
Perform CPR if necessary.
• Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema.
• Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs).
• As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semi-recumbent posture) and
must be kept under medical observation even if no symptoms are (yet) manifested.
• Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone derivative may be considered.
NOTES TO PHYSICIAN
■ Treat symptomatically.
For acute or short-term repeated exposures to highly alkaline materials:
• Respiratory stress is uncommon but present occasionally because of soft tissue edema.
• Unless endotracheal intubation can be accomplished under direct vision, cricothyroidotomy or tracheotomy may be necessary.
• Oxygen is given as indicated.
• The presence of shock suggests perforation and mandates an intravenous line and fluid administration.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
• Water spray or fog.
• Foam.
• Dry chemical powder.
• BCF (where regulations permit).
continued.
JASOL GRILLER
Chemwatch Material Safety Data Sheet
For Domestic Use Only.
CHEMWATCH 21-5472
Issue Date: 7-Jul-2009
Version No:2.0
CD 2010/2 Page 3 of 6
Section 5 - FIRE FIGHTING MEASURES
FIRE/EXPLOSION HAZARD
• Non combustible.
• Not considered a significant fire risk, however containers may burn.
May emit corrosive fumes.
FIRE INCOMPATIBILITY
■ None known.
Personal Protective Equipment
Gas tight chemical resistant suit.
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
• Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or disposal of material.
• Check regularly for spills and leaks.
• Clean up all spills immediately.
• Avoid breathing vapours and contact with skin and eyes.
• Control personal contact by using protective equipment.
• Contain and absorb spill with sand, earth, inert material or vermiculite.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
• DO NOT allow clothing wet with material to stay in contact with skin.
• Avoid all personal contact, including inhalation.
• Wear protective clothing when risk of exposure occurs.
• Use in a well-ventilated area.
• WARNING: To avoid violent reaction, ALWAYS add material to water and NEVER water to material.
SUITABLE CONTAINER
• Lined metal can, lined metal pail/ can.
• Plastic pail.
• Polyliner drum.
• Packing as recommended by manufacturer.
For low viscosity materials
• Drums and jerricans must be of the non-removable head type.
• Where a can is to be used as an inner package, the can must have a screwed enclosure. <</>.
STORAGE REQUIREMENTS
• Store in original containers.
• Keep containers securely sealed.
• Store in a cool, dry, well-ventilated area.
• Store away from incompatible materials and foodstuff containers.
• DO NOT store near acids, or oxidising agents.
• No smoking, naked lights, heat or ignition sources.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source
The following materials had no OELs on our records• water: PERSONAL PROTECTION
RESPIRATOR
Particulate
EYE
• Safety glasses with unperforated side shields may be used where continuous eye protection is desirable, as in laboratories; spectacles are not
sufficient where complete eye protection is needed such as when handling bulk-quantities, where there is a danger of splashing, or if the materialmay be under pressure continued.
JASOL GRILLER
Chemwatch Material Safety Data Sheet
For Domestic Use Only.
CHEMWATCH 21-5472
Issue Date: 7-Jul-2009
Version No:2.0
CD 2010/2 Page 4 of 6
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
• Chemical goggles.whenever there is a danger of the material coming in contact with the eyes; goggles must be properly fitted• Full face shield (20 cm, 8 in minimum) may be required for supplementary but never for primary protection of eyes; these afford face protection.
• Alternatively a gas mask may replace splash goggles and face shields.
HANDS/FEET
• Elbow length PVC gloves.
• When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.
Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: such as:
• frequency and duration of contact,
• chemical resistance of glove material,
• glove thickness and
• dexterity.
OTHER
• Overalls.
• PVC Apron.
• PVC protective suit may be required if exposure severe.
• Eyewash unit.
ENGINEERING CONTROLS
■ Local exhaust ventilation usually required. If risk of overexposure exists, wear approved respirator.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Clear, brown, viscous liquid; mixes with water.
PHYSICAL PROPERTIES
Mixes with water.
Corrosive.
Alkaline.
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
• Presence of incompatible materials.
• Product is considered stable.
• Hazardous polymerisation will not occur.
For incompatible materials - refer to Section 7 - Handling and Storage.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
■ The material can produce severe chemical burns within the oral cavity and gastrointestinal tract following ingestion.
■ The material can produce severe chemical burns to the eye following direct contact. Vapours or mists may be extremely irritating.
EYE
■ When applied to the eye(s) of animals, the material produces severe ocular lesions which are present twenty-four hours or more after instillation.
■ Direct contact with alkaline corrosives may produce pain and burns. Oedema, destruction of the epithelium, corneal opacification and iritis may
occur.
CHRONIC HEALTH EFFECTS
■ Repeated or prolonged exposure to corrosives may result in the erosion of teeth, inflammatory and ulcerative changes in the mouth and necrosis
(rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumonia may ensue.
Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and related systemic problems.
Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or biochemical
continued.
JASOL GRILLER
Chemwatch Material Safety Data Sheet
For Domestic Use Only.
CHEMWATCH 21-5472
Issue Date: 7-Jul-2009
Version No:2.0
CD 2010/2 Page 5 of 6
Section 11 - TOXICOLOGICAL INFORMATION
systems.
On the basis, primarily, of animal experiments, concern has been expressed that the material may produce carcinogenic or mutagenic effects; inrespect of the available information, however, there presently exists inadequate data for making a satisfactory assessment.
TOXICITY AND IRRITATION
■ Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic condition
known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating compound.
WARNING: This substance has been classified by the IARC as Group 2B: Possibly Carcinogenic to Humans.
Section 12 - ECOLOGICAL INFORMATION
This material and its container must be disposed of as hazardous waste.
Ecotoxicity
Ingredient
Section 13 - DISPOSAL CONSIDERATIONS
• Recycle where possible Otherwise ensure that:• licenced contractors dispose of the product and its container.
• disposal occurs at a licenced facility.
Section 14 - TRANSPORTATION INFORMATION
HAZCHEM:
2X
Shipping Name:CORROSIVE LIQUID, N.O.S. (contains sodium hydroxide) Air Transport IATA:
ICAO/IATA Class:
Shipping Name: CORROSIVE LIQUID, N.O.S. *(CONTAINS SODIUM HYDROXIDE) Maritime Transport IMDG:
IMDG Class:
Shipping Name: CORROSIVE LIQUID, N.O.S.(contains sodium hydroxide) Section 15 - REGULATORY INFORMATION
NOTES
This substance should be managed in accordance with the requirements specified in the Industrial and Institutional Cleaning Products (Corrosive,
Toxic [6.7]) Group Standard 2006, HSNO Approval Number HSR002588.
continued.
JASOL GRILLER
Chemwatch Material Safety Data Sheet
For Domestic Use Only.
CHEMWATCH 21-5472
Issue Date: 7-Jul-2009
Version No:2.0
CD 2010/2 Page 6 of 6
Section 15 - REGULATORY INFORMATION
REGULATIONS
Regulations for ingredients
sodium hydroxide (CAS: 1310-73-2) is found on the following regulatory lists;
"CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with
GMP","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","International Council of
Chemical Associations (ICCA) - High Production Volume List","New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of
Chemicals","New Zealand Hazardous Substances and New Organisms (HSNO) Act - Classification of Chemicals - Classification Data","New Zealand Hazardous
Substances and New Organisms (HSNO) Act - Scheduled Toxic Substances","New Zealand Inventory of Chemicals (NZIoC)","New Zealand Workplace Exposure
Standards (WES)","OECD Representative List of High Production Volume (HPV) Chemicals"
water (CAS: 7732-18-5) is found on the following regulatory lists;
"IMO IBC Code Chapter 18: List of products to which the Code does not apply","New Zealand Inventory of Chemicals (NZIoC)","OECD Representative List
of High Production Volume (HPV) Chemicals"
No data for Jasol Griller (CW: 21-5472)
Specific advice on controls required for materials used in New Zealand can be found athttp://www.ermanz.govt.nz/search/registers.html Section 16 - OTHER INFORMATION
NEW ZEALAND POISONS INFORMATION CENTRE0800 POISON (0800 764 766)NZ EMERGENCY SERVICES: 111■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references.
■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 7-Jul-2009Print Date: 29-Jul-2010

Source: http://www.jasol.co.nz/Common/Pdf/nz-msds/Chemwatch%20New%20Zealand%20MSDS%20Jasol%20Griller.pdf