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MSDS: VOLTEC LI-ION BATTERY (Not classified as hazardous) Material Safety Data Sheet
Infosafe™
Issue Date
September 2012 Status
Not classified as hazardous
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION Product Name
Product Use
Company Name
191 Salmon Street Port Melbourne Vic 3207 Emergency Tel.
Aust: 1800 638 556 NZ: 0800 154 666 (24 hours) Telephone
Number/Fax
Other Names
2. COMPOSITION/INFORMATION ON INGREDIENTS Composition,
information on Cell/Electrolyte Mixture:
ingredients
Chemical Cas No. Percent(%) Aluminium foil 7429-90-5 2-10 Metal oxide Proprietary 30-40 Manganese Proprietary 10-20 Nickel Proprietary 2-5 Cobalt Proprietary 2-5 Polyvinylidene Fluoride (PVDF) Proprietary <5 Copper Foil 7440-50-8 5-15 Carbon 7440-44-0 10-20 Electrolyte-organic carbonate Proprietary 10-20 Lithium Proprietary - Battery Cover: http://www.msdsonline.com.au/gmh/msds/msdsview.asp?SynonymCode=LQ1N300&. 13/11/2012 MSDS: VOLTEC LI-ION BATTERY (Not classified as hazardous) Chemical Cas No. Percent(%) SMC-type material NA NA Frames, Endplates, Hose Connections and Interconnect Boards: Chemical Cas No. Percent(%) 33% Fiberglass Reinforced Nylon 66 NA NA Not classified as Hazardous according to the Globally Harmonised System of Classification and labelling of Chemicals (GHS) including Work, Health and Safety regulations, Australia. Classified as Dangerous Goods according to the Australian Code for the Transport of Dangerous Goods by Road and Rail. (7th edition) Reproductive
Toxicity
Not considered to be toxic to reproduction.
Carcinogenicity The following components, that can be present at > 0.1%, are
listed in the NTP Annual Report on Carcinogens (latest edition) or have been found to be a potential carcinogen in the IARC Monographs (latest edition), or by OSHA: Cobalt: IARC 2B (Possibly Carcinogenic to Humans) Nickel: IARC 2B (Possibly Carcinogenic to Humans) and NTP (Reasonably Anticipated to be a Human Carcinogen).
Chronic Effects Prolonged contact with cell/electrolyte mixture may cause skin
Inhalation
Inhalation of vapours from an open battery may cause irritation of the respiratory system.
Ingestion
Not expected during normal use. Swallowing electrolyte mixture may cause gastrointestinal tract burns. May cause nausea and vomiting.
Contents of an open battery can be irritating or corrosive to skin. The symptoms may include redness, itching, swelling or burns.
Contents of an open battery can be severely irritating or corrosive to eyes. The symptoms may include redness, itching, blurred vision, tearing or burns and possible tissue injury.
Under normal conditions of use the battery is hermetically Information
sealed. This is a sealed article; although the contents are hazardous, the overall article is classified as non-hazardous. The battery should not be opened or burned. Exposure to ingredients contained within or their combustion products could be harmful. Exposure to the substances could occur only if the battery pack or cells have been opened, disassembled, crushed, burned, exposed to high temperatures >150°C, or subjected to other types of abuse. This battery has two significant characteristics: - Contains an electrolyte; and - Can contain a considerable amount of energy, which may be a source of high electric current and lead to a severe electrical shock in the event of a short circuit.
http://www.msdsonline.com.au/gmh/msds/msdsview.asp?SynonymCode=LQ1N300&. 13/11/2012 MSDS: VOLTEC LI-ION BATTERY (Not classified as hazardous) Inhalation
If inhaled, remove affected person from contaminated area. Keep at rest until recovered. If symptoms persist seek medical attention.
Ingestion
Do not induce vomiting. Wash out mouth thoroughly with water. Seek medical attention.
Wash affected area thoroughly with soap and water. Remove contaminated clothing and wash before reuse or discard. If symptoms develop seek medical attention.
If in eyes wash out immediately with water. Continue flushing for several minutes until all contaminants are washed off completely. Seek medical attention.
First Aid
Facilities
Advice to
Doctor
This information is of relevance only if the Battery is broken Information
and this results in a direct contact with the ingredients.
Extinguishing
Small Fire: Use ABC fire extinguisher or water spray. Specific
This product will burn under fire conditions. If heated above 150°C, battery or cell/electrolyte mixture may burst or rupture or vent.
Hazardous
Under fire conditions this product may emit toxic and/or Combustion
irritating fumes and gases including carbon monoxide, carbon Products
dioxide, hydrogen, hdrogen fluoride, aldehydes, metal oxides and C1-C3 hydrocarbons.
Decomposition
Temp.
Precautions in Fire fighters should wear Self-Contained Breathing Apparatus
connection with (SCBA) operated in positive pressure mode and full protective
Fire
clothing to prevent exposure to vapours or fumes.
Unsuitable
Extinguishing
Do not use extinguisher containing metal (Class D, type II Flash Point
Ignition
Temperature
Flammability
http://www.msdsonline.com.au/gmh/msds/msdsview.asp?SynonymCode=LQ1N300&. 13/11/2012 MSDS: VOLTEC LI-ION BATTERY (Not classified as hazardous) In case of leakage, wear appropriate personal protective equipment and clothing to prevent exposure. Remove all metal objects including rings, watches, belts, etc. before handling battery cells or packs. Extinguish or remove all sources of ignition and stop leak if safe to do so. Increase ventilation. Evacuate all unprotected personnel. For small releases, use paper towel or dry cloth to absorb electrolyte. For larger releases, cleanup all spills/leaks immediately using an inert absorbent (vermiculite, cat litter, dry sand). Place contaminated sorbent in appropriate container and dispose of waste in accordance with local regulations. After removing the battery/cell and absorbent material, clean area with soap and water. Collect the material and place into suitable labelled containers for subsequent recycling or disposal. Dispose of waste according to the applicable local and national regulations. If contamination of sewers or waterways occurs inform the local water and waste management authorities in accordance with local regulations.
Handling
Do not short circuit the battery. Prolonged short circuit will cause battery to lose energy, generate significant heat and can cause the safety release vent to open. Damaging a lithium battery can result in an internal short circuit. The contents of an open lithium battery, including a vented battery, when exposed to water, may result in a fire and/or explosion. Crushed or damaged batteries may result in a fire. Do not charge it in the unit. Do not disassemble the pack.
Store in a cool, dry, well-ventilated area away from sources of ignition, strong oxidising agents and strong acids. Elevated temperatures can result in shortened battery life. Protect against physical damage. Inspect regularly for deficiencies such as damage or leaks. Have appropriate fire extinguishers available in and near the storage area.
National
Exposure
No exposure value assigned for this specific material by the Standards
Safe Work, Australia. However, the available exposure limits for battery contents are given below: Safe Work, Australia Exposure Standards: Substance TWA STEL NOTICES ppm mg/m³ ppm mg/m³ Cobalt, metal dust & fume (as Co) - 0.05 - - Sen Aluminium (metal dust) - 10 - - - http://www.msdsonline.com.au/gmh/msds/msdsview.asp?SynonymCode=LQ1N300&. 13/11/2012 MSDS: VOLTEC LI-ION BATTERY (Not classified as hazardous) Aluminium (welding fumes) - 5 - - - Copper (dust & mist) - 1 - - - Copper (fume) - 0.2 - - - Nickel - 1 - - Sen TWA (Time Weighted Average): The average airborne concentration of a particular substance when calculated over a normal eight-hour working day, for a five-day week. STEL (Short Term Exposure Limit): The average airborne concentration over a 15 minute period which should not be exceeded at any time during a normal eight-hour workday.
Respiratory
Protection
Not required under normal conditions.
Eye Protection
Not required under normal conditions.
Hand Protection Wear insulated high voltage gloves for handling packs, or
neoprene or nitrile rubber gloves. Final choice of appropriate gloves will vary according to individual circumstances i.e. methods of handling or according to risk assessments undertaken. Reference should be made to AS/NZS 2161.1: Occupational protective gloves - Selection, use and maintenance.
Body Protection Suitable protective work wear, e.g. cotton overalls buttoned at
neck and wrist is recommended. Chemical resistant apron is recommended where large quantities are handled.
Eng. Controls
Not required under normal conditions.
Biological
Limit Values
Appearance
Cell: Aluminum Colored Sealed Unit Battery Pack: Black T-Shaped Sealed Assembly Decomposition
Temperature
Melting Point
Boiling Point
Solubility in
Water
Specific
Gravity (H2O=1) Not applicable for an article.
Vapour Pressure Not applicable for an article.
http://www.msdsonline.com.au/gmh/msds/msdsview.asp?SynonymCode=LQ1N300&. 13/11/2012 MSDS: VOLTEC LI-ION BATTERY (Not classified as hazardous) Vapour Density
(Air=1)
Evaporation
Rate
Coefficient
Water/Oil
Distr.
Odour Threshold Not applicable for an article.
Viscosity
Flash Point
Flammability
Ignition
Temperature
Explosion Limit
- Upper
Explosion Limit
- Lower
Stability
Stable under normal conditions of storage and handling.
Hazardous
Polymerization
Materials to
Avoid
Avoid exposure to heat, open flame, and corrosives.
Hazardous
At high temperatures toxic and/or corrosive compounds including Decomposition
carbon monoxide, carbon dioxide, hydrogen, hdrogen fluoride, Products
aldehydes, metal oxides and C1-C3 hydrocarbons.
Conditions to
Do not crush, puncture, incinerate, immerse in water or expose Toxicology
Information
No toxicity data available for this product.
Inhalation
Inhalation of vapours from an open battery may cause irritation of the respiratory system.
Ingestion
Not expected during normal use. Swallowing electrolyte mixture http://www.msdsonline.com.au/gmh/msds/msdsview.asp?SynonymCode=LQ1N300&. 13/11/2012 MSDS: VOLTEC LI-ION BATTERY (Not classified as hazardous) may cause gastrointestinal tract burns. May cause nausea and vomiting.
Contents of an open battery can be irritating or corrosive to skin. The symptoms may include redness, itching, swelling or burns.
Contents of an open battery can be severely irritating or corrosive to eyes. The symptoms may include redness, itching, blurred vision, tearing or burns and possible tissue injury.
Chronic Effects Prolonged contact with cell/electrolyte mixture may cause skin
Reproductive
Toxicity
Not considered to be toxic to reproduction.
Carcinogenicity The following components, that can be present at > 0.1%, are
listed in the NTP Annual Report on Carcinogens (latest edition) or have been found to be a potential carcinogen in the IARC Monographs (latest edition), or by OSHA: Cobalt: IARC 2B (Possibly Carcinogenic to Humans) Nickel: IARC 2B (Possibly Carcinogenic to Humans) and NTP (Reasonably Anticipated to be a Human Carcinogen).
Skin
Sensitisation
Not expected to be a skin sensitiser.
Overexposure to products generated from overcharge or combustion Information
of the cell or battery may result in simple and chemical asphyxiation. Symptoms may include rapid respiration, muscular incoordination, fatigue, dizziness, nausea, vomiting, unconsciousness, and death. Severe eye irritation or tissue injury may occur at high concentrations. Prolonged overexposure to decomposition products may adversely affect the lungs, blood, cardiovascular, and central nervous system. Symptoms may include headache, confusion, excitation, rapid breathing, an irregular heartbeat (arrhythmia), lassitude (weakness, exhaustion), cyanosis (bluish or purplish tinge to the skin), and chest pain.
Environment
Protection
Prevent this material entering waterways, drains and sewers.
Mobility
Persistence /
Degradability
Bioaccumulation Some substances within the cell/electrolyte mixture are
Ecotoxicity
In the case of a broken battery and leakage of the electrolyte solution, will react with water and organic substances, causing damage to flora and fauna. The electrolyte may also contain soluble components which can be toxic to aquatic environments http://www.msdsonline.com.au/gmh/msds/msdsview.asp?SynonymCode=LQ1N300&. 13/11/2012 MSDS: VOLTEC LI-ION BATTERY (Not classified as hazardous) This product can be disposed through a licensed commercial waste collection service, in accordance with applicable local and national regulations. Do not discharge into drains, sewers, waterways or soil.
Road and Rail Transport: This material is classified as a Class 9 (Miscellaneous Dangerous Goods) dangerous Goods according to The Australian Code for the Transport of Dangerous Goods by Road and Rail (7th edition). Class 9 Dangerous Goods are incompatible in a placard load with any of the following: - Class 1, Explosives (when the class 9 substance is a fire risk substance), - Division 5.1, Oxidizing agents (when the class 9 substance is a fire risk substance), and - Division 5.2, Organic peroxides (when the class 9 substance is a fire risk substance). However, this product is not recognised as 'DANGEROUS GOODS', when its transport condition accords with Special Provisions 188, 230 and 310 of the ADG Code. Marine Transport (IMO/IMDG): Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea. UN No.: 3480 Proper Shipping Name: LITHIUM ION BATTERIES DG Class: 9 Packaging Group: II EMS No.: F-A, S-I IMDG Marine Pollutant: N Special provision: 188, 230, 310, 348, 957 Air Transport (ICAO/IATA): Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air. UN No: 3480 Proper Shipping Name: : LITHIUM ION BATTERIES Class: 9 Packing Group: II Label: Miscellaneous Packing Instruction: 965 (For passenger and cargo aircraft) Packing Instruction: 965 (For cargo aircraft only) Special provision: A88, A99, A154, A164, A183 U.N. Number
Proper Shipping
Name
Hazchem Code
http://www.msdsonline.com.au/gmh/msds/msdsview.asp?SynonymCode=LQ1N300&. 13/11/2012 MSDS: VOLTEC LI-ION BATTERY (Not classified as hazardous) Packing Group
IERG Number
IMDG Marine
Pollutant (MP)
Not classified as Hazardous according to the Globally Harmonised System of Classification and labelling of Chemicals (GHS) including Work, Health and Safety regulations, Australia. Not classified as a Scheduled Poison according to the Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).
Safety Phrase
Poisons
Schedule
User Codes
User Title Label
User Code
http://www.msdsonline.com.au/gmh/msds/msdsview.asp?SynonymCode=LQ1N300&. 13/11/2012 MSDS: VOLTEC LI-ION BATTERY (Not classified as hazardous) SDS History
Poisons
Schedule
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