Material safety data sheet

MATERIAL SAFETY DATA SHEET Jin Gwang Industry Co.,Ltd “ConfiAd” Joint Adhesive, Component A & Component B 232-8 Maesan-ri Opo-eup, Gwangju-si, Gyeonggi-do,Korea 82-31-767-8441 2. COMPOSITION / INFORMATION ON INGREDIENTS 30~60% CAS Number : 80-62-6 EC Number : 201-297-1 REACH # : 05-2114088188-37-0000 (Pre-registration) CAS Number : 21645-51-2 EC Number : 244-492-7 : 05-2114088189-35-0000 (Pre-registration) Skin, eye and upper respiratory tract irritation. Central nervous system effects from inhalation overexposure. Information is provided for each component of the mixture to meet requirements of OSHA’s Hazard Communication Standard (29 CFR 1910.1200). The effects noted occur from exposure to the pure component unless otherwise noted. Liquid or mist will cause severe conjunctival irritation Material may cause irritation. repeated or prolonged contact may produce defatting of the skin leading to irritation and dermatitis. MATERIAL SAFETY DATA SHEET Jin Gwang Industry Co.,Ltd Swallowing may have the following effects: irritation of mouth, Health Effects-Ingestion throat and digestive tract. nausea. difficulty with breathing. Low volatility makes acute effects unlikely at ambient temperatures. Health Effects-Inhalation Increased susceptibility to the effects of Methyl methacylate may be observed in persons with pre-existing disease of the skin or lungs. Causes eye irritation. Causes redness and pain. Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. May be harmful if absorbed Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Health Effects-Ingestion May cause human systemic effects by ingestion: hallucinations, distorted perceptions, nausea or vomiting and kidney, ureter and bladder changes. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Health Effects-Inhalation Decomposition products are toxic, and inhalation of these products can produce life Increased susceptibility to the effects of Benzoyl peroxide may be observed in persons per-existing disease of the skin None of the components present in this material at concentrations equal to or greater than 1.1% are listed by IARC, NTP, OSHA or ACGIH as a carcinogen. Immediately flood the eye with plenty of water for at least 15 minutes. holding the eye open. Obtain medical attention urgently. Wash skin thoroughly with soap and water. Contaminated clothing should be washed or dry-cleaned before re-use. Wash out mouth with water. (Never administer anything by mouth if a casualty is losing consciousness, is unconscious or is Keep warm and at rest. If there is difficulty in breathing, give oxygen. If breathing stops or shows signs of failing, apply artificial respiration. Do not use mouth to mouth ventilation. Remove from exposure. Keep warm and at rest. If there is difficulty in breathing, give oxygen. If breathing stops or shows signs of failing, Obtain medical attention. Treat symptomatically. Flash point : 11 ℃ Method: TCC (for component A) Flash point : 191 ℃ Method: COC (for component B) MATERIAL SAFETY DATA SHEET Jin Gwang Industry Co.,Ltd Flammable liquid. Vapor forms explosive mixture with air. Vapors and gases are heavier than air and may travel considerable distance to an ignition source and flash back. Susceptible to spontaneous heating. Sealed containers may rupture explosively due to polymerization if exposed to elevated temperature. Peroxide and decomposition products are flammable and can be ignite with Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Keep containers and surroundings cool with water spray. This product may give rise to hazardous fumes in a fire. Wear self contained breathing apparatus. Try to prevent the material from entering drains or water courses. Advise Authorities if spillage has entered water course or sewer or has Contain and absorb using earth, sand or other inert material. Transfer into suitable containers for recovery of disposal. Keep container tightly closed when not in use. Use in well ventilated area. Avoid inhaling vapor. Avoid contact with eyes, skin and clothing. Emergency shower and eye wash facilities should be readily available. Use of non-sparking and explosion-proof equipment may be necessary depending on type of operation. Storage area should be cool, dry, well ventilated. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Material may cause irritation to mucous membranes, skin burns, eye corrosion and permanent injury. ( TLV : 100 ppm ) Engineering methods to prevent or control exposure are preferred. Methods include process or personnel enclosure, mechanical ventilation (dilution and local exhaust), and control of process conditions. If engineering controls and work practices are not effective in preventing or controlling exposure, then suitable personal protective equipment, which is known to perform satisfactorily, should be used. Respiratory protection if there is risk of breathing mists or vapors from heated Chemical goggles must be worn during all handling operations. If there is danger of splashing, wear impermeable suit. During application, adequate ventilation must be provided. MATERIAL SAFETY DATA SHEET Jin Gwang Industry Co.,Ltd (EXPOSURE CONTROLS / PERSONAL PROTECTION – Continued) PEL (OSHA) : 100ppm, 410mg/m3, 8 hrs, TWA TLV (ACGIH) : 50ppm, 8 hrs, TWA, STEL 100ppm, A4 Benzoyl Peroxide PEL (OSHA) : 5mg/m3, 8 hrs, TWA TLV (ACGIH) : 5 mg/m3, 8 hrs, TWA, A4 Viscous liquid (Component A) / Oily Liquid (Component B) Various (Component A) / Transparent (Component B) Acrylic (Component A) / Mild (Component B) Lower 2.1%, Upper 12.5% (Component A) / No data available (Component B) Slightly soluble (Component A) / Insoluble (Component B) 1.2 at 23℃ (Component A) / 1.1 at 23℃ (Component B) 22,000 / 60,000 at 23℃. (typical) (Component A) VOC Content Under 50 g/ℓ mixed (Component A) / None (Component B) 10. STABILITY AND REACTIVITY Heat, spark, flames and other sources of ignition. Oxidizing agents, Air, Amine, Strong acids. Combustion will generate : oxides of carbon, smoke, methyl methacrylate Polymer may be formed at high temperature or addition of oxidizing materials or Persistence/Degradability The product is expected to be partially or slowly biodegradable. Bio-accumulation The product is not expected to bioaccumulate. MATERIAL SAFETY DATA SHEET Jin Gwang Industry Co.,Ltd Dispose of in accordance with all applicable local and national regulations. Incineration is the recommended method of disposal. Empty containers may contain hazardous residues. Labels should not be removed from containers until they have been cleaned. Contaminated containers must not be treated as household waste. Containers should be disposed of by landfill or incineration as appropriate. Do not incinerate in closed containers. Do not flush to 14. TRANSPORT INFORMATION *** This information relates to the kit as a whole ( Component A, Component B ). Packing Group III* ICAO Labels : Flammable liquid Packing Group III* Labels : Flammable liquid Exception : For inner packaging not over 1.0 liter net capacity each and 30kg gross * Despite a flash point of 11℃, this product has been assigned to Packing Group III as per the USA TSCA, Europe EINECS, Canada DSL, Korea ECL/TCCL, Japan MITI(ENCS) EPA Sara Title III Hazard Acute : Yes Classification Section Responsible for the products user to determine at the time of disposal whether a material containing the product or derived from the product should be classified as Contents : Methyl Methacrylate, Alumina Trihydrate, Benzoyl Peroxide Always wear safety goggles and protective gloves. CONFIAD ADHESIVE should be stored in a cool and dark area. Avoid breathing vapor and use only with adequate ventilation. Keep away from heat, sparks, open flame and other combustible materials. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling MATERIAL SAFETY DATA SHEET Jin Gwang Industry Co.,Ltd R21 : harmful if contact with skin R22 : harmful if swallowed R36/37/38 : Irritating to eyes, respiratory system and skin R43 : May cause sensitization by skin contact S2 : Keep out of reach of children S7 : Keep container tightly closed when not in use S9 : Keep container in a well-ventilated place S15/16 : Keep away from heat and sources of ignition. No smoking S23 : Do not breathe vapor S24/25 : Avoid contact with skin and eyes S29 : Do not empty into drains S37 : Wear suitable gloves S51 : Use only in well ventilated area We hereby certify that the above statements are based upon technical information believed to be reliable. It is subject to revision as additional knowledge and experience is gained. Disclaimer : This MSDS is offered for your consideration and guidance when exposed to this product. Jin Gwang Industry Co., Ltd expressly disclaims all expressed or implied warranties and assumes no responsibilities for the accuracy or completeness of the data contained herein. The data in this MSDS does not apply to use with any other product or in any other process.


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